天元航材是一家生产销售端羟基聚丁二烯、氧化铬铜、copper chromite等化工原材料的厂家,其中亚铬酸铜的英文名称为copper chromite,亚铬酸铜是一种高效催化剂,它作为有机化合物的加氢脱水、环化、烷基化、苯胺转化二苯胺或制备已内酰胺等的催化剂,应用于有机反应中,那么您足够了解copper chromite吗?今天小编给大家介绍一下吧!
SAFETY
Risk and Safety Statements
Hazard Codes | >O,Xi |
---|---|
Risk Statements | 8-37-36/37/38-20/21 |
Safety Statements | 17-24/25-23 |
RIDADR | UN 1479 5.1/PG 2 |
WGK Germany | 3 |
HS Code | 28415000 |
Project name |
Index |
Test Method |
总六价铬(以 CrO42-计),%(m/m) | 15.5 ± 2.5 |
analysis by titration |
总三价铬(以Cr2O3计),%(m/m) |
28.5 ± 1.5 |
analysis by titration |
氧化铜(以CuO计),%(m/m) |
46.5 ± 1.5 |
analysis by titration |
650℃灼烧失重,% |
≤ 3.0 |
Loss on ignition method |
水份,%(m/m) |
≤0.7 |
Dry weight reduction method |
粒度(过120µm筛),% |
100 |
Sieving method |
Computational chemical data
- Hydrogen Bond Donor Count:0
- Molecular Weight: 131.5415g/mol
- Molecular Formula: CrCuO
- Compound Is Canonicalized: True
- XLogP3-AA:
- Exact Mass: 130.865016
- Monoisotopic Mass: 130.865016
-
- Covalently-Bonded Unit Count:3
- Complexity: 0
- Rotatable Bond Count: 0
- Isotope Atom Count:0
- Topological Polar Surface Area: 1
- Heavy Atom Count: 3
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count: 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
-
- Hydrogen Bond Acceptor Count:1
-
Computational Production
Copper chromite is produced by thermal decomposition of one of three substances.
Copper barium ammonium chromate is the most commonly used substance for production of copper chromite. The resulting copper chromite mixture produced by this method can only be used in procedures that contain materials inert to barium, as barium is a product of the decomposition of copper barium ammonium chromate, and is thus present in the resulting mixture. The by-product copper oxide is removed using an acetic acid extraction, consisting of washing with the acid,decantation and then heat drying of the remaining solid to yield isolated copper chromite. Copper chromite is produced by the exposure of copper barium ammonium chromate to temperatures of 350-450°C, generally by a muffle furnace.
Copper ammonium chromate is also used for production of copper chromite. It is generally utilized as an alternative to the route of barium ammonium chromate for usage in chemicals reactive with barium. This can also be washed with acetic acid and dried to remove impurities. Copper chromite is produced through the exposure of copper ammonium chromate to temperatures of 350-450°C:
An active copper chromite catalyst which includes barium in its structure can be prepared from a solution containing barium nitrate, copper(II) nitrate, and ammonium chromate. When these compounds are mixed a resulting precipitate is formed. This solid product is then calcined at 350–400°C to yield the catalyst